USSR (Engl. Your email address will not be published. It is the simplest carboxylate anion.A formate (compound) is a salt or ester of formic acid. ; Mookherjee,B.D. ; Maltby, D., Prediction of retention indexes. Corrections? One of the most common industrial uses of formic acid is in the production of leather. Some of formic acid esters are used as perfumes and deodorants. Formic acid is also prepared in the form of its esters by treatment of carbon monoxide with an alcohol such as methanol (methyl alcohol) in the presence of a catalyst. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Ants belong to the family of Formicidae, they spray formic acid from their body onto the enemies whenever they are attacked. 32, Pg. It is a colourless liquid with a pungent odour and has a sour taste. CH 3 OH + CO → HCO 2 CH 3. Degrad. Required fields are marked *. BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA. Hygroscopic: absorbs moisture or water from the air. Emeritus Professor of Chemistry, Beloit College, Wisconsin. Johannes Panten and Horst Surburg "Flavors and Fragrances, 2. Ammonia can be used. 199, 1994. [Note: Often used in an aqueous solution. Formic acid solution. Vol. Study of headspace sampling methods, Flavour Fragr. With methyl formate and formamide – When methanol reacts with water, methyl formate is formed. It is widely used as a food preservative. I. EC Number 200-579-1. Zeitschrift fuer Ernaehrungswissenschaft. ; Boulanger, R.; Barel, M.; Guyot, B.; Guiraud, J.-P.; Schorr-Galindo, S., Impact of "ecological" post-harvest processing of coffee aroma: II Roasted coffee., J. T. Reda, C. M. Plugge, N. J. Abram and J. Hirst, "Reversible interconversion of carbon dioxide and formate by an electroactive enzyme", PNAS 2008 105, 10654–10658. Formate (IUPAC name: methanoate) is the anion derived from formic acid. Formate (IUPAC name: methanoate) is the anion derived from formic acid.Its formula is represented in various equivalent ways: HCOO − or CHOO − or HCO 2 −.It is the product of deprotonation of formic acid. Methanoic acid, Formylic acid, Hydrogen carboxylic acid, Health: 3; Flammability: 2; Instability: 1. 332, 1969. Formic acid (ammonium salt) Mravencan amonny [Czech] HSDB 479. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Acetic formic anhydride. Molecular Formula: C3H4O3. is a naturally occurring substance, found due to forest emissions and in insects like bees and ants. Compared to the more common ethyl esters, formate esters are less commonly used commercially because they are less stable. ; Leguijt, T.; Nijhuis, H.H., Aroma profile development of intermediate chocolate products. Journal of Toxicology, Clinical Toxicology. 1 Product Result. Many form spontaneously when alcohols dissolve in formic acid. Labor Hygiene and Occupational Diseases. ; Pizzale, L.; Conte, L.S. ; Buxaderas, S.; Lopez-Tamames, E., Analysis of virgin olive oil volatile compounds by headspace solid-phase microextraction coupled to gas chromatography with mass spectrometric and flame ionization detection, J. Chromatogr. 24,25-dihydrolanosterol + 3 NADPH + 3 oxygen + 2 H+ -> 4,4-dimethyl-5-alpha-cholesta-8,14-dien-3-beta-ol + formate + 3 NADP+ + 4 H2O, 4-amino-2-methyl-5-diphosphomethylpyrimidine biosynthesis, 5-aminoimidazole ribonucleotide biosynthesis II, 6-hydroxymethyl-dihydropterin diphosphate biosynthesis I, androst-4-ene-3,17-dione + 3 a reduced [NADPH-hemoprotein reductase] + 3 oxygen -> estrone + 3 an oxidized [NADPH-hemoprotein reductase] + formate + 4 H2O + H+, flavin biosynthesis I (bacteria and plants), formaldehyde oxidation II (glutathione-dependent), formate assimilation into 5,10-methylenetetrahydrofolate, formate[out] + a menaquinone[membrane] + 2 H+[in] -> CO2[out] + a menaquinol[membrane] + H+[out], indole degradation to anthranil and anthranilate, lanosterol + 3 NADPH + 3 oxygen + 2 H+ -> 4,4-dimethyl-cholesta-8,14,24-trienol + formate + 3 NADP+ + 4 H2O, L-tryptophan degradation to 2-amino-3-carboxymuconate semialdehyde, pyrimidine deoxyribonucleotides de novo biosynthesis II, S-methyl-5-thio-alpha-D-ribose 1-phosphate degradation, S-methyl-5-thio-alpha-D-ribose 1-phosphate degradation I, superpathway of fermentation (Chlamydomonas reinhardtii), superpathway of pyrimidine deoxyribonucleotides de novo biosynthesis (E. coli), testosterone + 3 a reduced [NADPH-hemoprotein reductase] + 3 oxygen -> 17beta-estradiol + 3 an oxidized [NADPH-hemoprotein reductase] + formate + 4 H2O + H+, (S)-nicotine + 2 NADPH + 2 oxygen + H+ -> nornicotine + formate + 2 NADP+ + 2 H2O, 1,2-dihydroxy-5-(methylsulfanyl)pent-1-en-3-one + oxygen -> 3-(methylsulfanyl)propanoate + formate + carbon monoxide + H+, 1,2-dihydroxy-5-(methylsulfanyl)pent-1-en-3-one + oxygen -> 4-(methylsulfanyl)-2-oxobutanoate + formate + H+, 14-oxolanosterol + NADPH + oxygen -> 4,4-dimethyl-cholesta-8,14,24-trienol + formate + NADP+ + H2O, 19-oxoandrostenedione + a reduced [NADPH-hemoprotein reductase] + oxygen -> estrone + formate + an oxidized [NADPH-hemoprotein reductase] + H2O + H+, 19-oxo-testosterone + a reduced [NADPH-hemoprotein reductase] + oxygen -> 17beta-estradiol + formate + an oxidized [NADPH-hemoprotein reductase] + H2O + H+, 2-formylaminobenzaldehyde + H2O -> O-aminobenzaldehyde + formate + H+, 4,4-dimethyl-14alpha-formyl-5alpha-cholesta-8-en-3beta-ol + NADPH + oxygen -> 4,4-dimethyl-5-alpha-cholesta-8,14-dien-3-beta-ol + formate + NADP+ + H2O, 4alpha,14alpha-dimethyl-5alpha-cholesta-8,24-dien-3beta-ol + 3 NADPH + 3 NADPH + 2 H+ + 3 oxygen + 3 oxygen + 2 H+ -> formate + formate + 4alpha-methyl-5alpha-cholesta-8,14,24-trien-3beta-ol + 3 NADP+ + 3 NADP+ + 4 H2O + 4 H2O, 4alpha,14alpha-dimethyl-5alpha-cholesta-8,24-dien-3beta-ol + 3 NADPH + 3 oxygen + 2 H+ -> 4alpha-methyl-5alpha-cholesta-8,14,24-trien-3beta-ol + formate + 3 NADP+ + 4 H2O, 4alpha,14alpha-dimethyl-5alpha-cholesta-8,24-dien-3beta-ol + 3 NADPH + 3 oxygen + 2 H+ -> formate + 4alpha-methyl-5alpha-cholesta-8,14,24-trien-3beta-ol + 3 NADP+ + 4 H2O, a tetrahydrofolate + ATP + formate <--> an N10-formyl-tetrahydrofolate + ADP + phosphate, an N10-formyl-tetrahydrofolate + H2O -> a tetrahydrofolate + formate + H+, CO2[out] + H+[out] + 2 e-[membrane] -> formate[out], D-ribulose 5-phosphate -> formate + 1-deoxy-L-glycero-tetrulose 4-phosphate + H+, formate + acetyl-CoA <- pyruvate + coenzyme A, gamma-L-glutamyl-(S)-2-carboxypropyl-L-cysteine -> gamma-L-glutamyl-(S)-trans-1-propenyl-L-cysteine + formate, GTP + 3 H2O -> 2,5-diamino-6-(5-phospho-D-ribosylamino)pyrimidin-4(3H)-one + formate + diphosphate + 2 H+, GTP + H2O -> formate + 7,8-dihydroneopterin 3'-triphosphate + H+, N1-(5-phospho-beta-D-ribosyl)glycinamide + formate + ATP -> N2-formyl-N1-(5-phospho-beta-D-ribosyl)glycinamide + ADP + phosphate + H+, N-formyldemecolcine + H2O -> demecolcine + formate, N-formylkynurenine + H2O -> L-kynurenine + formate + H+, obtusifoliol + 3 NADPH + 3 oxygen + 2 H+ -> 4alpha-methyl-5alpha-ergosta-8,14,24(28)-trien-3beta-ol + formate + 3 NADP+ + 4 H2O, obtusifoliol + 3 NADPH + 3 oxygen + 2 H+ -> formate + 4alpha-methyl-5alpha-ergosta-8,14,24(28)-trien-3beta-ol + 3 NADP+ + 4 H2O, octadecanal + 2 NADPH + oxygen + H+ -> heptadecane + formate + 2 NADP+ + H2O, pyruvate + coenzyme A -> formate + acetyl-CoA, S-adenosyl-L-methionine + 5-amino-1-(5-phospho-beta-D-ribosyl)imidazole -> 4-amino-2-methyl-5-(phosphooxymethyl)pyrimidine + 5'-deoxyadenosine + L-methionine + formate + carbon monoxide + 3 H+, S-adenosyl-L-methionine + 5-amino-1-(5-phospho-beta-D-ribosyl)imidazole -> carbon monoxide + formate + L-methionine + 5'-deoxyadenosine + 4-amino-2-methyl-5-(phosphooxymethyl)pyrimidine + 4-amino-2-methyl-5-(phosphooxymethyl)pyrimidine + 5'-deoxyadenosine + L-methionine + formate + carbon monoxide + 3 H+ + 3 H+, S-formylglutathione + H2O -> formate + glutathione + H+.
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